2-Chloro-4-fluoro-N-phenylbenzamide
نویسندگان
چکیده
In the title compound, C(13)H(9)ClFNO, the dihedral angle between the two aromatic rings is 13.6 (2)°. In the crystal, the mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds into chains extending along the c-axis direction.
منابع مشابه
4-Chloro-N-phenylbenzamide
In the title compound, C(13)H(10)ClNO, the dihedral angle between the two benzene rings is 59.6 (1)°. The crystal structure features N-H⋯O hydrogen bonds, which link the mol-ecules into C(4) chains running along the a axis.
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In the title compound, C(13)H(10)ClNO, the meta-chloro group on the benzoyl ring is positioned syn to the C=O bond. The two aromatic rings make a dihedral angle of 88.5 (3)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into C(4) chains propagating in [010].
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Chlorination of 3-fluoro-2-methyl-aniline with N-chloro-succinimide gave one major regioisomer whose structure was determined by X-ray crystallography. The product was found to have cocrystallized with succinimide, giving the title compound, C(7)H(7)ClFN·C(4)H(5)NO(2). The crystal structure is stabilized by N-H⋯O hydrogen-bonding and π-π stacking inter-actions with a centroid-centroid distance ...
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